Showing posts with label crystal. Show all posts
Showing posts with label crystal. Show all posts

Sunday, May 2, 2010

Topaz : as a mineral

Topaz :as a mineralsource : Wikipedia, the free encyclopedia

Topaz is a silicate mineral of aluminium and fluorine with the chemical formula Al2SiO4(F,OH)2. Topaz crystallizes in the orthorhombic system and its crystals are mostly prismatic terminated by pyramidal and other faces.

Color and varieties

Pure topaz is colorless and transparent but is usually tinted by impurities; typical topaz is wine, yellow, pale gray or reddish-orange, blue brown. It can also be made white, pale green, blue, gold, pink (rare), reddish-yellow or opaque to transparent/translucent.

Orange topaz, also known as precious topaz, is the traditional November birthstone, the symbol of friendship, and the state gemstone for the US State of Utah

Imperial topaz is yellow, pink (rare, if natural) or pink-orange. Brazilian Imperial Topaz can often have a bright yellow to deep golden brown hue, sometimes even violet. Many brown or pale topazes are treated to make them bright yellow, gold, pink or violet colored. Some imperial topaz stones can fade on exposure to sunlight for an extended period of time.Blue topaz is the Texas state gemstone. Naturally occurring Blue Topaz is quite rare. Typically, colorless, gray or pale yellow and blue material is heat treated and irradiated to produce a more desired darker blue.

Mystic topaz is colorless topaz which has been artificially coated giving it the desired rainbow effect.


Localities and occurrence

Topaz Mountain, Utah

<-Topaz Mountain, Utah
Topaz is commonly associated with silicic igneous rocks of the Topaz is commonly associated with silicicgranite and rhyolite type. It typically crystallizes in granitic pegmatites or in vapor cavities in rhyolite lava flows like those at Topaz Mountain in western Utah. It can be found with fluorite and cassiterite in various areas including Ural and Ilmen mountains of Russia, in Afghanistan, Sri Lanka, Czech Republic, Germany, Norway, Pakistan, Italy, Sweden, Japan, Brazil, Mexico, Flinders Island, Australia and the United States.

Some clear topaz crystals from Brazilian pegmatites can reach boulder size and weigh hundreds of pounds. Crystals of this size may be seen in museum collections. The Topaz of Aurungzebe, observed by Jean Baptiste Tavernier measured 157.75 carats.

Colorless and light-blue varieties of topaz are found in Precambrian granite in Mason County, Texas within the Llano Uplift. There is no commercial mining of topaz in that area.

Colorless topaz, Minas Gerais, Brazil
Colorless topaz, Minas Gerais, Brazil






A cut blue topazA cut blue topaz







A red topazA red topaz





Imperial Topaz GemImperial Topaz Gem







Facet Cut Topaz Gemstones in various colors, including mysticFacet Cut Topaz Gemstones in various colors, including mystic.




Etymology and historical and mythical usage

The name "topaz" is derived (via Old French: Topace and Latin: Topazus) from the Greek Τοπάζιος (Τοpáziοs) or Τοπάζιον (Τοpáziοn), the ancient name of St. John's Island in the Red Sea which was difficult to find and from which a yellow stone (now believed to be chrysolite: yellowish olivine) was mined in ancient times; topaz itself (rather than topazios) wasn't really known about before the classical era. Nicols, the author of one of the first systematic treatises on minerals and gemstones, dedicated two chapters to the topic in 1652. In the Middle Ages, the name topaz was used to refer to any yellow gemstone, but in modern times it denotes only the silicate described above.

Many modern English translations of the Bible, including the King James Version mention Topaz in Exodus 28:17 in reference to a stone in the Hoshen: "And thou shalt set in it settings of stones, even four rows of stones: the first row shall be a sardius, a topaz, and a carbuncle (Garnet): this shall be the first row."

However, because these translations as topaz all derive from the Septuagint translation topazi[os], which as mentioned above referred to a yellow stone that was not topaz, but probably chrysolite, it should be borne in mind that topaz is not meant here.The masoretic text (the Hebrew on which most modern Protestant Bible translations of the Old Testament are based) has pitdah as the gem the stone is made from; some scholars think it is related to an Assyrian word meaning flashed.More likely, pitdah is derived from Sanskrit words (पीत pit = yellow, दह् dah = burn), meaning "yellow burn". Pliny says that Topazos is a legendary island in the Red Sea and the mineral "topaz" was first mined there. The word topaz might be related to the Arabic word توباز which meant "the subject of the search" or Sanskrit word तपस् "tapas" meaning "heat" or "fire."

source : wikipeadia

Thursday, December 6, 2007

Amethyst : as a mineral

Amethyst is a purple variety of quartz often used as an ornament. The name comes from the Greek a ("not") and methustos ("to intoxicate"), a reference to the belief that the stone protected its owner from drunkenness; the ancient Greeks and Romans wore amethyst and made drinking vessels of it in the belief that it would prevent intoxication.
Quartz
Amethyst
General
Category Mineral variety
Chemical formula Silica (silicon dioxide, SiO2)
Identification
Color purple
Crystal habit 6-sided prism ending in 6-sided pyramid (typical)
Crystal system rhombohedral class 32
Twinning Dauphine law, Brazil law and Japan law
Cleavage None
Fracture Conchoidal
Mohs Scale hardness 7 - lower in impure varieties
Luster Vitreous/glossy
Refractive index nω = 1.543 - 1.553 nε = 1.552 - 1.554
Optical Properties Uniaxial (+) (Positive)
Birefringence +0.009 (B-G interval)
Pleochroism None
Streak White
Specific gravity 2.65 constant; variable in impure varieties
Melting point 1650 (±75) °C
Solubility H2O insoluble
Diaphaneity Transparent to translucent
Other Characteristics Piezoelectric
Chemistry

Amethyst is the purple variety of quartz, its chemical formula is SiO2.

In the 20th century, the color of amethyst was attributed to the presence of manganese. However, since it is capable of being greatly altered and even discharged by heat, the color was believed by some authorities to be from an organic source. Ferric thiocyanate was suggested, and sulfur was said to have been detected in the mineral.

More recent work has shown that amethyst's coloration is due to ferric iron impurities.[1] Further study has shown a complex interplay of iron and aluminium is responsible for the color.[2]

On exposure to heat, amethyst generally becomes yellow, and much of the citrine, cairngorm, or yellow quartz of jewelry is said to be merely "burnt amethyst." Veins of amethystine quartz are apt to lose their color on the exposed outcrop[citation needed].

Synthetic amethyst is made to imitate the best quality amethyst. Its chemical and physical properties are so similar to that of natural amethyst that it cannot be differentiated with absolute certainty without advanced gemological testing (which is often cost prohibitive). There is one test (which is not 100 percent certain) based on "Brazil law twinning" (a form of quartz twinning where right and left hand quartz structures are combined in a single crystal[3] which can be used to identify synthetic amethyst rather easily. In theory however it is possible to create this material synthetically as well, but this type is not available in large quantities in the market.[4]

Composition

Amethyst is composed of an irregular superposition of alternate lamellae of right-handed and left-handed quartz. It has been shown that this structure may be due to mechanical stresses. As a consequence of this composite formation, amethyst is apt to break with a rippled fracture or to show "thumb markings," and the intersection of two sets of curved ripples may produce on the fractured surface a pattern something like that of "engine turning." Some mineralogists, following Sir David Brewster, apply the name of amethyst to all quartz which exhibits this structure, regardless of color.

Because it has a hardness of 7 on the Mohs scale, amethyst is treasured for its use in jewelry.

Hue and Tone

Amethyst occurs in a continuum of primary hues from a light slightly pinkish violet to a deep grape purple. Amethyst may exhibit one or both secondary hues, red and/or blue. The ideal grade is called "Deep Siberian" and has a primary purple hue of around 75 - 80 percent, 15-20 percent blue and (depending on the light source) red secondary hues.[4]

A polished amethyst gem stone.

A polished amethyst gem stone.

History

Amethyst was used as a gemstone by the ancient Egyptians and was largely employed in antiquity for intaglios. Beads of amethyst are found in Anglo-Saxon graves in England. It is a widely distributed mineral, but fine, clear specimens that are suitable for cutting as ornamental stones are confined to comparatively few localities. Such crystals occur either in the cavities of mineral-veins and in granitic rocks, or as a lining in agate geodes. A huge geode, or "amethyst-grotto," from near Santa Cruz in southern Brazil was exhibited at the Düsseldorf, Germany Exhibition of 1902. Many of the hollow agates of Brazil and Uruguay contain a crop of amethyst crystals in the interior. Much fine amethyst comes from Russia, especially from near Mursinka in the Ekaterinburg district, where it occurs in drusy cavities in granitic rocks. Many localities in India yield amethyst.

Museum-quality piece of Amethyst

Museum-quality piece of Amethyst

Geographic distribution

Amethyst occurs at many localities in the United States, but these specimens are rarely fine enough for use in jewelry. Among these may be mentioned Amethyst Mountain, Texas; Yellowstone National Park; Delaware County, Pennsylvania; Haywood County, North Carolina; Deer Hill and Stow, Maine. It is found also in the Lake Superior region. Amethyst is relatively common in northwestern Ontario, and in various locations throughout Nova Scotia, but uncommon elsewhere in Canada. Amethyst is produced in abundance from the state of Minas Gerais in Brazil where it occurs in large geodes within volcanic rocks. It is also found and mined in South Korea. The largest opencast amethyst vein in the world is in Maissau, Lower Austria.

6 carat (1.2 g) pear shape amethyst ring

6 carat (1.2 g) pear shape amethyst ring

Value

Traditionally included in the cardinal, or most valuable, gemstones (along with diamond, sapphire, ruby, and emerald), amethyst has lost much of its value due to the discovery of extensive deposits in locations such as Brazil. The highest grade Amethyst (called "Deep Russian") is exceptionally rare and therefore its value is dependent on the demand of collectors when one is found. It is however still orders of magnitude lower than the highest grade sapphires or rubies (Padparadscha Sapphire or "Pigeon Blood" Ruby) which can go for as much as $50,000 or more per carat.[4]

Amethyst such as the "Russian" quality (bluish purple key color) and such as material recently found in Georgia since 2005 (with some of the stones showing both blue hue and red flashes) and of which its top material is considered of the best quality presently available [5] still command prices of not more than $50 per carat.[6]

Amethyst in folklore and astrology

Amethyst is the birthstone associated with February. It is also associated with the astrological signs of Pisces, Aries (especially the violet and purple variety), Aquarius, and Sagittarius. It is a symbol of heavenly understanding, and of the pioneer in thought and action on the philosophical, religious, spiritual, and material planes. Ranking members of the Roman Catholic Church traditionally wear rings set with a large amethyst as part of their office.

The Greek word "amethystos" (αμέθυστος) basically can be translated as "not drunken." Amethyst was considered to be a strong antidote against drunkenness, which is why wine goblets were often carved from it. Supposedly, when a drunken Dionysus was pursuing a maiden called Amethystos, who refused his affections, she prayed to the gods to remain chaste. The goddess Artemis granted the prayer, transforming her into a white stone; humbled by Amethystos' desire to remain chaste, Dionysus poured wine over the stone she had become as an offering, dyeing the crystals purple.

Variants of the story include that Dionysus, the god of intoxication, had been insulted by a mortal and swore revenge on the next mortal who crossed his path, creating fierce tigers to carry out his wish; the mortal turned out to be a beautiful young woman, Amethystos, who was on her way to pay tribute to Artemis. Her life is spared by Artemis, who transforms the maiden into a statue of pure crystalline quartz to protect her from the brutal claws. Dionysus wept tears of wine in remorse for his action at the sight of the beautiful statue. The god's tears stained the quartz purple.[7] Another variation involves the goddess Rhea presenting Dionysus with the amethyst stone to preserve the winedrinker's sanity.[8]

Notes

  1. ^ Klein, Cornelis and Hurlbut, Cornelius S., 1985 Manual of Mineralogy (after JD Dana) 20th edition, p. 441, John Wiley & Sons, New York
  2. ^ Cohen, Alvin J., 1985, Amethyst color in quartz,the result of radiation protection involving iron', American Mineralogist, V. 70, pp 1180-1185
  3. ^ Quartz Page Twinning Crystals. Retrieved on 2007-05-28.
  4. ^ a b c Secrets of the Gem Trade; The Connoisseur's Guide to Precious Gemstones Richard W Wise, Brunswick House Press, Lenox, Massachutes., 2003
  5. ^ Bowling, Ryan L (2005). "Jackson Crossroads Amethyst Deposit, Wilkes County, Georgia". Mineralogical Record A 36 (6): 479(8). Retrieved on 2007-05-27.
  6. ^ Mountain Gems and Minerals, Little Switzerland, NC; one of the authors or Mineralogical Record and other articles and co-owner of the mine. Tucson showreport images: http://www.gamineral.org/t05-clarion_hotel.html
  7. ^ source
  8. ^ (Nonnus, Dionysiaca, XII.380)
source : http://en.wikipedia.org/wiki/Amethyst